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Preheat oven to 350 degrees and grease your pie pan.
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Microwave 4 oz of the chocolate along with the butter in large microwavable bowl. Start with 1-2 minutes; once the butter is melted, try stirring the mixture to see if any remaining chocolate will also melt.
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Add sugar to the chocolate/butter mixture.
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Stir in eggs and vanilla.
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Add flour, baking powder, and salt - make sure to mix well.
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Chop the 4 oz refrigerated chocolate bar and fold into the other mixture. The bar will chop up into smaller pieces more easily if it is cold.
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Add the pecans.
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Spread evenly into the pie pan. I wanted my dessert to have a little bit of a crust, so I let the edges sit up a little higher than the middle. This is not necessary. You can lay the batter evenly if you desire as well.
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Bake around 30 minutes, checking a few minutes before. With the chopped chocolate and therefore fudgy brownie, remember that doing the toothpick trick is a little bit harder. When you take it out of the oven, take a small knife and run along the outside edge of the pan to help ensure nothing is sticking.
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Once cooled, put the icing on top.